Advance on nickel‐ and <scp>palladium‐catalyzed</scp> insertion copolymerization of ethylene and acrylate monomers
نویسندگان
چکیده
Abstract Nickel‐ and palladium‐catalyzed insertion copolymerization of ethylene acrylate comonomers for synthesis ethylene‐acrylates copolymers have attracted much academic industrial interests remained highly challenging. This review provides an overview the developments in nickel‐ comonomers. Mechanistic interpretation metal‐catalyzed is described. Late transition metal catalysts are divided to nickel‐based palladium‐based with different chelate ligands. The effects catalyst structure on performance copolymer microstructure comprehensively discussed. aims promote design development nickel palladium ethylene/acrylate copolymerizations copolymers.
منابع مشابه
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ژورنال
عنوان ژورنال: Journal of polymer science
سال: 2023
ISSN: ['1542-9385', '0098-1273']
DOI: https://doi.org/10.1002/pol.20230389